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dc.creatorRamalho, Teodorico C.-
dc.creatorMartins, Tales L. C.-
dc.creatorBorges, Luiz E. Pizarro-
dc.creatorPinho, Marcos Henrique de-
dc.creatorAvillez, Roberto Ribeiro de-
dc.creatorCunha, Elaine F. F. da-
dc.identifier.citationRAMALHO, T. C. et al. Influence of Zn–Cd substitution: Spectroscopic and theoretical investigation of 8-hydroxyquinoline complexe. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Amsterdam, v. 72, n. 4, p. 726-729, May 2009.pt_BR
dc.description.abstractIt is now well known that zinc is crucial for the synthesis of nucleic acids and, consequently, for cellular division. However, 67Zn, the NMR-detectable isotope, is one of the isotopes most poorly studied by NMR. The strategy used for NMR studies is the substitution of Zn by 113Cd. In this work, we employed 13C, 113Cd NMR (CPMAS), X-ray and DFT calculation in order to evaluate the Zn–Cd substitution using 8-hydroxyquinoline like prototype compound. Our results show that there are strong structural and electronics effects are involved in the substitution.pt_BR
dc.sourceSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopypt_BR
dc.subjectZinc complexespt_BR
dc.subjectCadmium complexespt_BR
dc.subjectCation substitutionpt_BR
dc.subjectDiscrete Fourier transformpt_BR
dc.subjectNucleic acidspt_BR
dc.subjectNuclear magnetic resonancept_BR
dc.subjectCellular divisionpt_BR
dc.subjectComplexos de zincopt_BR
dc.subjectComplexos de cádmiopt_BR
dc.subjectSubstituição catiônicapt_BR
dc.subjectTeoria do funcional da densidadept_BR
dc.subjectÁcidos nucleicospt_BR
dc.subjectRessonância magnética nuclearpt_BR
dc.subjectDivisão celularpt_BR
dc.titleInfluence of Zn–Cd substitution: Spectroscopic and theoretical investigation of 8-hydroxyquinoline complexespt_BR
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