Please use this identifier to cite or link to this item: http://repositorio.ufla.br/jspui/handle/1/37132
metadata.artigo.dc.title: Study of the influence of pH and of the interactions involved in etheramine removal in kaolinite: insights about adsorption mechanism
metadata.artigo.dc.creator: Magriotis, Zuy Maria
Sales, Priscila Ferreira de
Ramalho, Teodorico Castro
Rocha, Marcus Vinícius Juliaci
Leal, Paulo Vitor Brandão
metadata.artigo.dc.subject: Adsorption
Chemical interactions
Etheramine
Kaolinite
metadata.artigo.dc.publisher: ACS Publications (American Chemical Society)
metadata.artigo.dc.identifier.citation: MAGRIOTIS, Z. M. et al. Study of the influence of pH and of the interactions involved in etheramine removal in kaolinite: insights about adsorption mechanism. The Journal of Physical Chemistry C, Washington, DC, v. 117, p. 21788-21794, 2013. DOI: 10.1021/jp4054764.
metadata.artigo.dc.description.abstract: As the adsorption process involves interactions between molecules of the adsorbate and the surface of the adsorbent material, theoretical studies are developed with the aim of elucidating the mechanism. In this work, the influence of pH on adsorption of etheramine in kaolinite was investigated. The results showed that adsorption was most efficient at pH 10, which was attributed to the equilibrium of the etheramine molecules between ionic and molecular forms creating an ionic–molecular complex that promotes adsorption. Theoretical calculations confirmed these results and showed that the ionic–molecular dimer is the most stable structure among the possible dimers (ionic-ionic, molecular-molecular, and ionic-molecular).
metadata.artigo.dc.identifier.uri: https://pubs.acs.org/doi/10.1021/jp4054764
http://repositorio.ufla.br/jspui/handle/1/37132
metadata.artigo.dc.language: en_US
Appears in Collections:DEG - Artigos publicados em periódicos

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.