Please use this identifier to cite or link to this item: http://repositorio.ufla.br/jspui/handle/1/41818
metadata.artigo.dc.title: 1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugation
metadata.artigo.dc.creator: Freitas, Matheus P.
Bühlb, Michael
O'Hagan, David
metadata.artigo.dc.subject: 1,2-Difluoroethane
Gauche effect
Hyperconjugation
metadata.artigo.dc.publisher: Royal Society of Chemistry (RSC)
metadata.artigo.dc.date.issued: Jan-2012
metadata.artigo.dc.identifier.citation: FREITAS, M. P.; BUHL, M.; O'HAGAN, D. 1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugation. Chemical Communications, [S.l.], v. 48, p. 2433-2435, Jan. 2012.
metadata.artigo.dc.description.abstract: 1,2-Difluoroethane is widely recognised to adopt a lower energy gauche rather than anti conformation; this gauche effect has its origin in hyperconjugation; however, surprisingly the 1JCF coupling constant is not influenced by hyperconjugation; instead, its magnitude changes with the overall molecular dipole.
metadata.artigo.dc.identifier.uri: https://pubs.rsc.org/en/content/articlelanding/2012/CC/c2cc17180e#!divAbstract
http://repositorio.ufla.br/jspui/handle/1/41818
metadata.artigo.dc.language: en_US
Appears in Collections:DQI - Artigos publicados em periódicos

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