Use este identificador para citar ou linkar para este item: http://repositorio.ufla.br/jspui/handle/1/41845
Título: The reverse fluorine Perlin-like effect and related stereoelectronic interactions
Palavras-chave: Electrostatics
Fluorine
Molecular properties
Molecular structure
Gases
Data do documento: 6-Jun-2014
Editor: American Chemical Society (ACS)
Citação: SILLA, J. M. et al. The reverse fluorine Perlin-like effect and related stereoelectronic interactions. Journal of Organic Chemistry, [S.l.], v. 79, n. 13, p. 6385-6388, June 2014. DOI: 10.1021/jo501025a.
Resumo: A similar effect to the well-known reverse Perlin effect was observed on the 1JC–F coupling constants of α- and β-d-glucopyranosyl fluoride tetracetate, both in nonpolar and polar solution. This can be called “reverse fluorine Perlin-like effect”, and it is shown to be ruled by dipolar interactions rather than by hyperconjugation. The reverse fluorine Perlin-like effect does not have a general relationship with the anomeric effect, and it can be useful to determine the structure and stereochemistry of organofluorine compounds.
URI: https://pubs.acs.org/doi/10.1021/jo501025a
http://repositorio.ufla.br/jspui/handle/1/41845
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