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|metadata.artigo.dc.title:||Solution blow spun nanocomposites of poly(lactic acid)/cellulose nanocrystals from Eucalyptus kraft pulp|
|metadata.artigo.dc.creator:||Parize, Delne Domingos da Silva|
Oliveira, Juliano Elvis de
Avena-Bustillos, Roberto de Jesús
Klamczynski, Artur Piotr
Glenn, Gregory Melvin
Marconcini, José Manoel
Mattoso, Luiz Henrique Capparelli
Solution blow spinning
|metadata.artigo.dc.identifier.citation:||PARIZE, D. D. da S. et al. Solution blow spun nanocomposites of poly(lactic acid)/cellulose nanocrystals from Eucalyptus kraft pulp. Carbohydrate Polymers, [S.l.], v. 174, p. 923-932, Oct. 2017.|
|metadata.artigo.dc.description.abstract:||Cellulose nanocrystals (CNCs) were extracted from Eucalyptus kraft pulp by sulfuric acid hydrolysis, and esterified with maleic anhydride (CNCMA). The incorporation of sulfate ester groups on the cellulose surface resulted in higher stability of the nanoparticles in aqueous suspensions and lower thermal stability. Then, PLA/CNC and PLA/CNCMA nanocomposites were successfully obtained by solution blow spinning (SBS) using dimethyl carbonate (DMC) as solvent. CNC and CNCMA indicated to be acting both as nucleating agents or growth inhibitors of PLA crystal and tends to favor the formation of PLA crystals of higher stability. A fraction of the nanocrystals indicate to be exposed on the surface of the PLA fibers, since the hydrophilicity of the composite films increased significantly. Such composites may have potential application as filtering membranes or adsorbents.|
|Appears in Collections:||DEG - Artigos publicados em periódicos|
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