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Title: | Esterificação de ácidos graxos utilizando zircônia sulfatada e compósitos carvão ativado/zircônia sulfatada como catalisadores |
Other Titles: | Esterification of fatty acids using sulfated zirconia and composites activated carbon/sulfated zirconia catalysts |
Keywords: | Acid catalysis Esterification Biodiesel |
Issue Date: | Sep-2011 |
Publisher: | Sociedade Brasileira de Química (SBQ) |
Citation: | BRUM, S. S. et al. Esterificação de ácidos graxos utilizando zircônia sulfatada e compósitos carvão ativado/zircônia sulfatada como catalisadores. Química Nova, São Paulo, v. 34, n. 9, p. 1511-1516, Sept. 2011. DOI: 10.1590/S0100-40422011000900006. |
Abstract: | In this work sulfated zirconia (SZr) and activated carbon/SZr composites produced by impregnation method with or without heating treatment step (CABC/SZr-I and CABC/SZr-I SC) and by the method of synthesis of SZr on the carbon (CABC/SZr-S) was used as catalysts in the esterification reactions of fatty acids. The SZr presented very active, conversions higher than 90% were obtained after 2 h of reaction. The activity of the composite CABC/SZr-I20%SC was up to 92%, however, this was directly related to time and temperature reactions. CABC/SZr-I and CABC/SZr-S were less active in esterification reactions, what could be attributed to its low acidity. |
URI: | http://repositorio.ufla.br/jspui/handle/1/41883 |
Appears in Collections: | DQI - Artigos publicados em periódicos |
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File | Description | Size | Format | |
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ARTIGO_Esterificação de ácidos graxos utilizando zircônia sulfatada e compósitos carvão ativado zircônia sulfatada como catalisadores.pdf | 487,02 kB | Adobe PDF | View/Open |
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