1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugation
| dc.creator | Freitas, Matheus P. | |
| dc.creator | Bühlb, Michael | |
| dc.creator | O'Hagan, David | |
| dc.date.accessioned | 2020-07-12T23:07:03Z | |
| dc.date.available | 2020-07-12T23:07:03Z | |
| dc.date.issued | 2012-01 | |
| dc.description.abstract | 1,2-Difluoroethane is widely recognised to adopt a lower energy gauche rather than anti conformation; this gauche effect has its origin in hyperconjugation; however, surprisingly the 1JCF coupling constant is not influenced by hyperconjugation; instead, its magnitude changes with the overall molecular dipole. | pt_BR |
| dc.identifier.citation | FREITAS, M. P.; BUHL, M.; O'HAGAN, D. 1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugation. Chemical Communications, [S.l.], v. 48, p. 2433-2435, Jan. 2012. | pt_BR |
| dc.identifier.uri | https://repositorio.ufla.br/handle/1/41818 | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2012/CC/c2cc17180e#!divAbstract | pt_BR |
| dc.language | en_US | pt_BR |
| dc.publisher | Royal Society of Chemistry (RSC) | pt_BR |
| dc.rights | openAccess | pt_BR |
| dc.source | Chemical Communications | pt_BR |
| dc.subject | 1,2-Difluoroethane | pt_BR |
| dc.subject | Gauche effect | pt_BR |
| dc.subject | Hyperconjugation | pt_BR |
| dc.title | 1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugation | pt_BR |
| dc.type | Artigo | pt_BR |
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