1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugation

dc.creatorFreitas, Matheus P.
dc.creatorBühlb, Michael
dc.creatorO'Hagan, David
dc.date.accessioned2020-07-12T23:07:03Z
dc.date.available2020-07-12T23:07:03Z
dc.date.issued2012-01
dc.description.abstract1,2-Difluoroethane is widely recognised to adopt a lower energy gauche rather than anti conformation; this gauche effect has its origin in hyperconjugation; however, surprisingly the 1JCF coupling constant is not influenced by hyperconjugation; instead, its magnitude changes with the overall molecular dipole.pt_BR
dc.identifier.citationFREITAS, M. P.; BUHL, M.; O'HAGAN, D. 1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugation. Chemical Communications, [S.l.], v. 48, p. 2433-2435, Jan. 2012.pt_BR
dc.identifier.urihttps://repositorio.ufla.br/handle/1/41818
dc.identifier.urihttps://pubs.rsc.org/en/content/articlelanding/2012/CC/c2cc17180e#!divAbstractpt_BR
dc.languageen_USpt_BR
dc.publisherRoyal Society of Chemistry (RSC)pt_BR
dc.rightsopenAccesspt_BR
dc.sourceChemical Communicationspt_BR
dc.subject1,2-Difluoroethanept_BR
dc.subjectGauche effectpt_BR
dc.subjectHyperconjugationpt_BR
dc.title1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugationpt_BR
dc.typeArtigopt_BR

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