Gauche preference of β-fluoroalkyl ammonium salts

dc.creator	Silla, Josué M.
dc.creator	Silva, Weslley G. D. P.
dc.creator	Cormanich, Rodrigo A.
dc.creator	Rittner, Roberto
dc.creator	Tormena, Cláudio F.
dc.creator	Freitas, Matheus P.
dc.date.accessioned	2020-07-12T23:33:25Z
dc.date.available	2020-07-12T23:33:25Z
dc.date.issued	2013-12-30
dc.description.abstract	The strong gauche preference along with the F–C–C–N+ fragment in 3-fluoropiperidinium cation and analogues, in the gas phase, is dictated by electrostatic interactions, which can be both hydrogen bond F···H(N+) and F/N+ attraction. In aqueous solution, where most biochemical processes take place, electrostatic effects are strongly attenuated and hyperconjugation is calculated to be at least competitive with Lewis-type interactions.	pt_BR
dc.identifier.citation	SILLA, J. M. et al. Gauche preference of β-fluoroalkyl ammonium salts. The Journal of Physical Chemistry A, [S.l.], v. 118, n. 2, p. 503-507, Dec. 2013. DOI: 10.1021/jp410458w.	pt_BR
dc.identifier.uri	https://repositorio.ufla.br/handle/1/41839
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/jp410458w	pt_BR
dc.language	en_US	pt_BR
dc.publisher	American Chemical Society (ACS)	pt_BR
dc.rights	openAccess	pt_BR
dc.source	The Journal of Physical Chemistry A	pt_BR
dc.subject	Electrostatics	pt_BR
dc.subject	Molecular properties	pt_BR
dc.subject	Conformation	pt_BR
dc.subject	Molecular structure	pt_BR
dc.subject	Cations	pt_BR
dc.title	Gauche preference of β-fluoroalkyl ammonium salts	pt_BR
dc.type	Artigo	pt_BR

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