Effect of P/Ni ratio on the performance of nickel phosphide phases supported on zirconia for the hydrodeoxygenation of M-cresol

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dc.creatorGonçalves, Vinicius Ottonio O.
dc.creatorSouza, Priscilla M. de
dc.creatorCabioc'h, Thierry
dc.creatorSilva, Victor Teixeira da
dc.creatorNoronha, Fabio B.
dc.creatorRichard, Frédéric
dc.date.accessioned2020-05-15T17:57:57Z
dc.date.available2020-05-15T17:57:57Z
dc.date.issued2019
dc.description.abstractThe catalytic performances of various nickel phosphide catalysts (NiP) supported on ZrO2 synthesized with different P/Ni molar ratios (0.8, 2 and 3) were investigated in hydrodeoxygenation (HDO) of m-cresol at 340 °C under 4 MPa. The solid sample with the highest P/Ni ratio (NiP-3/ZrO2) presented the best catalytic performances in terms of activity, which were attributed to the presence of the pure Ni2P phase, the other samples containing either a mixture of Ni2P and Ni12P5 (NiP-2/ZrO2) or Ni12P5 (NiP-0.8/ZrO2) alone were less active. The use of ZrO2 as support required a large excess of P to obtain Ni2P as active phase.pt_BR
dc.identifier.citationGONÇALVES, V. O. O. et al. Effect of P/Ni ratio on the performance of nickel phosphide phases supported on zirconia for the hydrodeoxygenation of M-cresol. Catalysis Communications, [S.l.], v. 119, p. 33-38, 2019.pt_BR
dc.identifier.urihttps://repositorio.ufla.br/handle/1/40945
dc.identifier.urihttp://www.sciencedirect.com/science/article/pii/S1566736718305211pt_BR
dc.languageen_USpt_BR
dc.publisherElsevierpt_BR
dc.rightsopenAccesspt_BR
dc.sourceCatalysis Communicationspt_BR
dc.subjectM-cresolpt_BR
dc.subjectHydrodeoxygenation (HDO)pt_BR
dc.subjectNickel phosphide catalystspt_BR
dc.titleEffect of P/Ni ratio on the performance of nickel phosphide phases supported on zirconia for the hydrodeoxygenation of M-cresolpt_BR
dc.typeArtigopt_BR

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