An anomalous effect of fluorine on the conformational equilibrium of 2-fluorocyclohexane-1,3-dione

Página do item simplificado
dc.creatorAndrade, Laize A. F.
dc.creatorSilla, Josué M.
dc.creatorFreitas, Matheus P.
dc.date.accessioned2020-05-12T18:27:00Z
dc.date.available2020-05-12T18:27:00Z
dc.date.issued2019-01-24
dc.description.abstractConformational stabilities of 2-halocyclohexane-1,3-diones are strongly affected by steric and dipolar effects involving the carbonyl groups and the equatorial halogen. However, 2-fluorocyclohexane-1,3-dione has been found to be mostly equatorial, because of electron delocalization in this conformer that overcomes repulsive interactions, while the other halogen derivatives perform as expected.pt_BR
dc.identifier.citationANDRADE, L. A. F.; SILLA, J. M.; FREITAS. M. P. An anomalous effect of fluorine on the conformational equilibrium of 2-fluorocyclohexane-1,3-dione. Tetrahedron Letters, Elmsford, v. 60, n. 4, p. 355-357, 24 Jan. 2019.pt_BR
dc.identifier.urihttps://repositorio.ufla.br/handle/1/40845
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0040403918315065#!pt_BR
dc.languageen_USpt_BR
dc.publisherElsevierpt_BR
dc.rightsopenAccesspt_BR
dc.sourceTetrahedron Letterspt_BR
dc.subjectConformation analysispt_BR
dc.subjectOrganofluorine compoundspt_BR
dc.subjectSteric effectpt_BR
dc.subjectDipolar interactionpt_BR
dc.subjectHyperconjugationpt_BR
dc.subjectAnálise de conformaçãopt_BR
dc.subjectCompostos organofluoradospt_BR
dc.subjectEfeito estéricopt_BR
dc.subjectInteração dipolarpt_BR
dc.subjectHiperconjugaçãopt_BR
dc.titleAn anomalous effect of fluorine on the conformational equilibrium of 2-fluorocyclohexane-1,3-dionept_BR
dc.typeArtigopt_BR

Arquivos

Licença do pacote

Agora exibindo 1 - 1 de 1
Imagem de Miniatura
Nome:
license.txt
Tamanho:
953 B
Formato:
Item-specific license agreed upon to submission
Descrição:
Baixar

Coleções

DQI - Artigos publicados em periódicos